{"id":43499,"date":"2022-05-11T00:00:00","date_gmt":"2022-05-11T00:00:00","guid":{"rendered":"https:\/\/discover.restek.com\/uncategorized\/japanese-optimized-polycyclic-aromatic-hydrocarbon-pah-analysis-by-gc-ms\/"},"modified":"2025-12-31T14:59:05","modified_gmt":"2025-12-31T14:59:05","slug":"japanese-optimized-polycyclic-aromatic-hydrocarbon-pah-analysis-by-gc-ms","status":"publish","type":"post","link":"https:\/\/discover.restek.com\/ja\/articles-ja\/evfa3822-ja\/japanese-optimized-polycyclic-aromatic-hydrocarbon-pah-analysis-by-gc-ms","title":{"rendered":"GC-MS\u306b\u3088\u308b\u591a\u74b0\u82b3\u9999\u65cf\u70ad\u5316\u6c34\u7d20 (PAH) \u5206\u6790\u306e\u6700\u9069\u5316"},"content":{"rendered":"\n<ul class=\"wp-block-list\">\n<li>Rxi-SVOCms\u30ab\u30e9\u30e0\u306f\u3001\u74b0\u5883\u4e2d\u306e\u91cd\u8981\u306aPAH\u5316\u5408\u7269\u306b\u5bfe\u3057\u3066\u826f\u597d\u306a\u5206\u96e2\u3068\u30ec\u30b9\u30dd\u30f3\u30b9\u3092\u3082\u305f\u3089\u3057\u307e\u3059\u3002<\/li>\n\n\n\n<li>\u4f4e\u30ab\u30e9\u30e0\u30d6\u30ea\u30fc\u30c9\u306b\u3088\u308a\u3001\u6eb6\u51fa\u306e\u9045\u3044\u5316\u5408\u7269\u306e\u6b63\u78ba\u3055\u304c\u78ba\u4fdd\u3055\u308c\u307e\u3059\u3002<\/li>\n\n\n\n<li>\u30b9\u30d7\u30ea\u30c3\u30c8\u6ce8\u5165\u306eSIM\u5206\u6790\u306f\u3001\u6ce8\u5165\u53e3\u3067\u306e\u30c7\u30a3\u30b9\u30af\u30ea\u30df\u30cd\u30fc\u30b7\u30e7\u30f3\u3092\u6700\u5c0f\u9650\u306b\u6291\u3048\u307e\u3059\u3002<\/li>\n<\/ul>\n\n\n\n<p>\u591a\u74b0\u82b3\u9999\u65cf\u70ad\u5316\u6c34\u7d20\uff08PAH\uff09\u306f\u3001\u4e3b\u306b\u70ad\u5316\u6c34\u7d20\u3092\u542b\u3080\u7269\u8cea\u306e\u4e0d\u5b8c\u5168\u71c3\u713c\u306b\u3088\u3063\u3066\u3001\u81ea\u7136\u306b\u3001\u305d\u3057\u3066\u4eba\u9593\u6d3b\u52d5\u306b\u3088\u3063\u3066\u3082\u5f62\u6210\u3055\u308c\u308b\u504f\u5728\u7684\u306a\u74b0\u5883\u6c5a\u67d3\u7269\u8cea\u3067\u3059\u3002\u591a\u74b0\u82b3\u9999\u65cf\u70ad\u5316\u6c34\u7d20\u306e\u4e2d\u306b\u306f\u767a\u304c\u3093\u6027\u306e\u3082\u306e\u304c\u3042\u308b\u305f\u3081\u3001\u5927\u6c17\u3001\u6c34\u3001\u571f\u58cc\u30b5\u30f3\u30d7\u30eb\u306e\u5fae\u91cf\u30ec\u30d9\u30eb\u306e\u30e2\u30cb\u30bf\u30ea\u30f3\u30b0\u306f\u66dd\u9732\u8a55\u4fa1\u306b\u4e0d\u53ef\u6b20\u3067\u3059\u3002Rxi-SVOCms\u30ab\u30e9\u30e0\u3092\u7528\u3044\u305fGC-MS\u306b\u3088\u308bPAH\u5206\u6790\u306f\u3001\u4ee5\u4e0b\u306b\u793a\u3059\u6700\u9069\u5316\u3055\u308c\u305f\u6761\u4ef6\u4e0b\u3067\u3001\u6700\u3082\u95a2\u9023\u6027\u306e\u9ad8\u3044\u5316\u5408\u7269\u3092\u52b9\u679c\u7684\u306b\u691c\u51fa\u3059\u308b\u3053\u3068\u304c\u3067\u304d\u307e\u3059\u3002<\/p>\n\n\n\n<p>\u96e3\u6613\u5ea6\u306e\u9ad8\u3044\u30b3\u30fc\u30eb\u30bf\u30fc\u30eb\u30b5\u30f3\u30d7\u30eb\u306b\u304a\u3044\u3066\u3001SIM\u30e2\u30fc\u30c9\u3068\u30b9\u30d7\u30ea\u30c3\u30c8\u6ce8\u5165\u3092\u4f7f\u7528\u3057\u3066\u6ce8\u5165\u53e3\u30c7\u30a3\u30b9\u30af\u30ea\u30df\u30cd\u30fc\u30b7\u30e7\u30f3\u3092\u6700\u5c0f\u9650\u306b\u6291\u3048\u305f\u3068\u3053\u308d\u3001\u69d8\u3005\u306aPAH\u5316\u5408\u7269\u306b\u5bfe\u3057\u3066\u826f\u597d\u306a\u30af\u30ed\u30de\u30c8\u30b0\u30e9\u30d5\u30a3\u30fc\u6027\u80fd\u304c\u78ba\u8a8d\u3055\u308c\u307e\u3057\u305f\u3002\u63ee\u767a\u6027\u306e\u6eb6\u51fa\u304c\u65e9\u3044\u5316\u5408\u7269\u306f\u826f\u597d\u306a\u30d4\u30fc\u30af\u5f62\u72b6\u3068\u30ec\u30b9\u30dd\u30f3\u30b9\u3092\u793a\u3059\u4e00\u65b9\u3001\u4f4e\u30ab\u30e9\u30e0\u30d6\u30ea\u30fc\u30c9\u306b\u3088\u308a\u3001\u30d0\u30c3\u30af\u30b0\u30e9\u30a6\u30f3\u30c9\u5e72\u6e09\u306f\u6700\u5c0f\u9650\u306b\u306a\u308a\u3001\u6eb6\u51fa\u306e\u9045\u3044\u5316\u5408\u7269\u306e\u611f\u5ea6\u304c\u6539\u5584\u3055\u308c\u307e\u3057\u305f\u3002 \u307e\u305f\u3001Rxi-SVOCms\u30ab\u30e9\u30e0\u306e\u52b9\u7387\u3068\u9078\u629e\u6027\u306b\u3088\u308a\u3001\u30d9\u30f3\u30be[b]\u30d5\u30eb\u30aa\u30e9\u30f3\u30c6\u30f3\u3084\u30d9\u30f3\u30be[k]\u30d5\u30eb\u30aa\u30e9\u30f3\u30c6\u30f3\u306a\u3069\u306e\u30a2\u30a4\u30bd\u30d0\u30ea\u30c3\u30afPAH\u3082\u826f\u597d\u306b\u5206\u96e2\u3067\u304d\u307e\u3057\u305f\u3002 \u30a4\u30f3\u30c7\u30ce[123-cd]\u30d4\u30ec\u30f3\u3084\u30b8\u30d9\u30f3\u30be[ah]\u30a2\u30f3\u30c8\u30e9\u30bb\u30f3\u306b\u3064\u3044\u3066\u3082\uff08\u30ec\u30b9\u30dd\u30f3\u30b9\u306b\u504f\u308a\u304c\u3042\u308b\u5834\u5408\u3067\u3082\uff09\u826f\u597d\u306a\u5206\u96e2\u304c\u5f97\u3089\u308c\u3001\u504f\u3063\u305f\u7d50\u679c\u3084\u507d\u967d\u6027\u306e\u5831\u544a\u306e\u53ef\u80fd\u6027\u3092\u6700\u5c0f\u9650\u306b\u6291\u3048\u3089\u308c\u307e\u3059\u3002<\/p>\n\n\n<div class=\"wp-block-custom-chromatogram-article-top\"><div class=\"chromatogram-article-placeholder\"><div class=\"figure-heading\"><strong>\u56f3 1:<\/strong>\u00a0Rxi-SVOCms \u30ab\u30e9\u30e0\u306e\u52b9\u7387\u3068\u9078\u629e\u6027\u306b\u3088\u308a\u3001GC-MS\u306b\u3088\u308bPAH\u5206\u6790\u306b\u304a\u3044\u3066\u91cd\u8981\u306a\u30da\u30a2\u306e\u512a\u308c\u305f\u5206\u96e2\u306f\u78ba\u5b9f\u306a\u3082\u306e\u3068\u306a\u308a\u307e\u3059\u3002<\/div><div class='chromatogram-article-inner-full'><div class=\"chromatogram-article-inner\">\n<div class=\"wp-block-custom-chromatogram-article\"><div class=\"wp-block-custom-chromatogram-article\"><div class=\"chromatogram-image wide-image\"><img decoding=\"async\" src=\"https:\/\/ez.restek.com\/images\/cgram\/gc_ev1606.png\" alt=\"Complex Mixture of Polycyclic Aromatic Hydrocarbons from Coal Tar on Rxi-SVOCms (SIM)\" title=\"-\"><\/div><p class=\"article-id\" style=\"text-align:center\"> GC_EV1606<\/p><div class=\"chromatogram-peaks\"><h4>Peaks<\/h4><table class=\"peaks col-lg-6 col-12 peak-50\">\n<thead><tr><th><\/th><th style=\"text-align: left;width: 75px\">Peaks<\/th><th style=\"text-align: center;width: 50px\">t<sub>R<\/sub> (min)<\/th><\/tr><\/thead>\n<tbody><tr><td class=\"num\">1.<\/td><td class=\"cmpd\"><a class=\"cmpd_link\" title=\"View compound information for Naphthalene\" href=\"https:\/\/ez.restek.com\/compound\/view\/en\/91-20-3\/Naphthalene\" target=\"_blank\" rel=\"noopener\">Naphthalene<\/a><\/td><td class=\"oth\">6.27<\/td><\/tr>\n<tr><td class=\"num\">2.<\/td><td class=\"cmpd\"><a class=\"cmpd_link\" title=\"View compound information for 2-Methylnaphthalene\" href=\"https:\/\/ez.restek.com\/compound\/view\/en\/91-57-6\/2-Methylnaphthalene\" target=\"_blank\" rel=\"noopener\">2-Methylnaphthalene<\/a><\/td><td class=\"oth\">7.09<\/td><\/tr>\n<tr><td class=\"num\">3.<\/td><td class=\"cmpd\"><a class=\"cmpd_link\" title=\"View compound information for 1-Methylnaphthalene\" href=\"https:\/\/ez.restek.com\/compound\/view\/en\/90-12-0\/1-Methylnaphthalene\" target=\"_blank\" rel=\"noopener\">1-Methylnaphthalene<\/a><\/td><td class=\"oth\">7.21<\/td><\/tr>\n<tr><td class=\"num\">4.<\/td><td class=\"cmpd\"><a class=\"cmpd_link\" title=\"View compound information for Biphenyl\" href=\"https:\/\/ez.restek.com\/compound\/view\/en\/92-52-4\/Biphenyl\" target=\"_blank\" rel=\"noopener\">Biphenyl<\/a><\/td><td class=\"oth\">7.66<\/td><\/tr>\n<tr><td class=\"num\">5.<\/td><td class=\"cmpd\"><a class=\"cmpd_link\" title=\"View compound information for 2,6-Dimethylnaphthalene\" href=\"https:\/\/ez.restek.com\/compound\/view\/en\/581-42-0\/2,6-Dimethylnaphthalene\" target=\"_blank\" rel=\"noopener\">2,6-Dimethylnaphthalene<\/a><\/td><td class=\"oth\">7.84<\/td><\/tr>\n<tr><td class=\"num\">6.<\/td><td class=\"cmpd\"><a class=\"cmpd_link\" title=\"View compound information for Acenaphthylene\" href=\"https:\/\/ez.restek.com\/compound\/view\/en\/208-96-8\/Acenaphthylene\" target=\"_blank\" rel=\"noopener\">Acenaphthylene<\/a><\/td><td class=\"oth\">8.17<\/td><\/tr>\n<tr><td class=\"num\">7.<\/td><td class=\"cmpd\"><a class=\"cmpd_link\" title=\"View compound information for (IS) Acenaphthene-d10\" href=\"https:\/\/ez.restek.com\/compound\/view\/en\/15067-26-2\/(IS) Acenaphthene-d10\" target=\"_blank\" rel=\"noopener\">(IS) Acenaphthene-d10<\/a><\/td><td class=\"oth\">8.35<\/td><\/tr>\n<tr><td class=\"num\">8.<\/td><td class=\"cmpd\"><a class=\"cmpd_link\" title=\"View compound information for Acenaphthene\" href=\"https:\/\/ez.restek.com\/compound\/view\/en\/83-32-9\/Acenaphthene\" target=\"_blank\" rel=\"noopener\">Acenaphthene<\/a><\/td><td class=\"oth\">8.39<\/td><\/tr>\n<tr><td class=\"num\">9.<\/td><td class=\"cmpd\"><a class=\"cmpd_link\" title=\"View compound information for 2,3,5-Trimethylnaphthalene\" href=\"https:\/\/ez.restek.com\/compound\/view\/en\/2245-38-7\/2,3,5-Trimethylnaphthalene\" target=\"_blank\" rel=\"noopener\">2,3,5-Trimethylnaphthalene<\/a><\/td><td class=\"oth\">8.86<\/td><\/tr>\n<tr><td class=\"num\">10.<\/td><td class=\"cmpd\"><a class=\"cmpd_link\" title=\"View compound information for Fluorene\" href=\"https:\/\/ez.restek.com\/compound\/view\/en\/86-73-7\/Fluorene\" target=\"_blank\" rel=\"noopener\">Fluorene<\/a><\/td><td class=\"oth\">9.02<\/td><\/tr>\n<tr><td class=\"num\">11.<\/td><td class=\"cmpd\"><a class=\"cmpd_link\" title=\"View compound information for Dibenzothiophene\" href=\"https:\/\/ez.restek.com\/compound\/view\/en\/132-65-0\/Dibenzothiophene\" target=\"_blank\" rel=\"noopener\">Dibenzothiophene<\/a><\/td><td class=\"oth\">10.03<\/td><\/tr>\n<tr><td class=\"num\">12.<\/td><td class=\"cmpd\"><a class=\"cmpd_link\" title=\"View compound information for (IS) Phenanthrene-D10\" href=\"https:\/\/ez.restek.com\/compound\/view\/en\/1517-22-2\/(IS) Phenanthrene-D10\" target=\"_blank\" rel=\"noopener\">(IS) Phenanthrene-D10<\/a><\/td><td class=\"oth\">10.16<\/td><\/tr>\n<tr><td class=\"num\">13.<\/td><td class=\"cmpd\"><a class=\"cmpd_link\" title=\"View compound information for Phenanthrene\" href=\"https:\/\/ez.restek.com\/compound\/view\/en\/85-01-8\/Phenanthrene\" target=\"_blank\" rel=\"noopener\">Phenanthrene<\/a><\/td><td class=\"oth\">10.19<\/td><\/tr>\n<\/tbody><\/table>\n<table class=\"peaks col-lg-6 col-12 peak-50\"><thead><tr><th><\/th><th style=\"text-align: left;width: 75px\">Peaks<\/th><th style=\"text-align: center;width: 50px\">t<sub>R<\/sub> (min)<\/th><\/tr><\/thead><tbody>\n<tr><td class=\"num\">14.<\/td><td class=\"cmpd\"><a class=\"cmpd_link\" title=\"View compound information for Anthracene\" href=\"https:\/\/ez.restek.com\/compound\/view\/en\/120-12-7\/Anthracene\" target=\"_blank\" rel=\"noopener\">Anthracene<\/a><\/td><td class=\"oth\">10.25<\/td><\/tr>\n<tr><td class=\"num\">15.<\/td><td class=\"cmpd\"><a class=\"cmpd_link\" title=\"View compound information for 1-Methylphenanthrene\" href=\"https:\/\/ez.restek.com\/compound\/view\/en\/832-69-9\/1-Methylphenanthrene\" target=\"_blank\" rel=\"noopener\">1-Methylphenanthrene<\/a><\/td><td class=\"oth\">10.95<\/td><\/tr>\n<tr><td class=\"num\">16.<\/td><td class=\"cmpd\"><a class=\"cmpd_link\" title=\"View compound information for Fluoranthene\" href=\"https:\/\/ez.restek.com\/compound\/view\/en\/206-44-0\/Fluoranthene\" target=\"_blank\" rel=\"noopener\">Fluoranthene<\/a><\/td><td class=\"oth\">11.65<\/td><\/tr>\n<tr><td class=\"num\">17.<\/td><td class=\"cmpd\"><a class=\"cmpd_link\" title=\"View compound information for Pyrene\" href=\"https:\/\/ez.restek.com\/compound\/view\/en\/129-00-0\/Pyrene\" target=\"_blank\" rel=\"noopener\">Pyrene<\/a><\/td><td class=\"oth\">11.92<\/td><\/tr>\n<tr><td class=\"num\">18.<\/td><td class=\"cmpd\"><a class=\"cmpd_link\" title=\"View compound information for Benz[a]anthracene\" href=\"https:\/\/ez.restek.com\/compound\/view\/en\/56-55-3\/Benz[a]anthracene\" target=\"_blank\" rel=\"noopener\">Benz[a]anthracene<\/a><\/td><td class=\"oth\">13.46<\/td><\/tr>\n<tr><td class=\"num\">19.<\/td><td class=\"cmpd\"><a class=\"cmpd_link\" title=\"View compound information for (IS) Chrysene-D12\" href=\"https:\/\/ez.restek.com\/compound\/view\/en\/1719-03-5\/(IS) Chrysene-D12\" target=\"_blank\" rel=\"noopener\">(IS) Chrysene-D12<\/a><\/td><td class=\"oth\">13.47<\/td><\/tr>\n<tr><td class=\"num\">20.<\/td><td class=\"cmpd\"><a class=\"cmpd_link\" title=\"View compound information for Chrysene\" href=\"https:\/\/ez.restek.com\/compound\/view\/en\/218-01-9\/Chrysene\" target=\"_blank\" rel=\"noopener\">Chrysene<\/a><\/td><td class=\"oth\">13.51<\/td><\/tr>\n<tr><td class=\"num\">21.<\/td><td class=\"cmpd\"><a class=\"cmpd_link\" title=\"View compound information for Benzo[b]fluoranthene*\" href=\"https:\/\/ez.restek.com\/compound\/view\/en\/205-99-2\/Benzo[b]fluoranthene\" target=\"_blank\" rel=\"noopener\">Benzo[b]fluoranthene*<\/a><\/td><td class=\"oth\">15.14<\/td><\/tr>\n<tr><td class=\"num\">22.<\/td><td class=\"cmpd\"><a class=\"cmpd_link\" title=\"View compound information for Benzo[k]fluoranthene\" href=\"https:\/\/ez.restek.com\/compound\/view\/en\/207-08-9\/Benzo[k]fluoranthene\" target=\"_blank\" rel=\"noopener\">Benzo[k]fluoranthene<\/a><\/td><td class=\"oth\">15.19<\/td><\/tr>\n<tr><td class=\"num\">23.<\/td><td class=\"cmpd\"><a class=\"cmpd_link\" title=\"View compound information for (SS) Benzo[a]pyrene-d12\" href=\"https:\/\/ez.restek.com\/compound\/view\/en\/63466-71-7\/(SS) Benzo[a]pyrene-d12\" target=\"_blank\" rel=\"noopener\">(SS) Benzo[a]pyrene-d12<\/a><\/td><td class=\"oth\">15.66<\/td><\/tr>\n<tr><td class=\"num\">24.<\/td><td class=\"cmpd\"><a class=\"cmpd_link\" title=\"View compound information for Benzo[a]pyrene\" href=\"https:\/\/ez.restek.com\/compound\/view\/en\/50-32-8\/Benzo[a]pyrene\" target=\"_blank\" rel=\"noopener\">Benzo[a]pyrene<\/a><\/td><td class=\"oth\">15.70<\/td><\/tr>\n<tr><td class=\"num\">25.<\/td><td class=\"cmpd\"><a class=\"cmpd_link\" title=\"View compound information for Indeno[1,2,3-cd]pyrene\" href=\"https:\/\/ez.restek.com\/compound\/view\/en\/193-39-5\/Indeno[1,2,3-cd]pyrene\" target=\"_blank\" rel=\"noopener\">Indeno[1,2,3-cd]pyrene<\/a><\/td><td class=\"oth\">17.78<\/td><\/tr>\n<tr><td class=\"num\">26.<\/td><td class=\"cmpd\"><a class=\"cmpd_link\" title=\"View compound information for Dibenz[a,h]anthracene\" href=\"https:\/\/ez.restek.com\/compound\/view\/en\/53-70-3\/Dibenz[a,h]anthracene\" target=\"_blank\" rel=\"noopener\">Dibenz[a,h]anthracene<\/a><\/td><td class=\"oth\">17.83<\/td><\/tr>\n<tr><td class=\"num\">27.<\/td><td class=\"cmpd\"><a class=\"cmpd_link\" title=\"View compound information for Benzo[ghi]perylene\" href=\"https:\/\/ez.restek.com\/compound\/view\/en\/191-24-2\/Benzo[ghi]perylene\" target=\"_blank\" rel=\"noopener\">Benzo[ghi]perylene<\/a><\/td><td class=\"oth\">18.27<\/td><\/tr>\n<\/tbody><\/table><div class=\"peaknotes\">* Benzo[b]fluoranthene and benzo[j]fluoranthene coelution.<\/div><\/div><div class=\"chromatogram-conditions\"><h4>Conditions<\/h4><div class=\"conditions-container container-fluid\"><div class=\"row\"><table class=\"conditions col-lg-6 col-12\"><tr><th class=\"conditions_header\" scope=\"row\">Column<\/th><td>Rxi-SVOCms, 30 m, 0.25 mm ID, 0.25 \u00b5m (<a target=\"_blank\" href=\"https:\/\/www.restek.com\/p\/16623?utm_source=chromatograms&amp;utm_medium=link&amp;utm_campaign=GC_EV1606\" rel=\"noopener\">cat.# 16623<\/a>)<\/td><\/tr><tr class=\"cgram_header_row\"><th class=\"conditions_header\" scope=\"row\">Standard\/Sample<\/th><td>NIST SRM 1597a &#8211; complex mixture of polycyclic aromatic hydrocarbons from coal tar<\/td><\/tr>\n<tr><th class=\"sub conditions_header\" scope=\"row\">Diluent:<\/th><td>Dichloromethane<\/td><\/tr><tr class=\"cgram_header_row\"><th class=\"conditions_header\" scope=\"row\">Injection<\/th><td><\/td><\/tr><tr><th class=\"sub conditions_header\" scope=\"row\">Inj. Vol.:<\/th><td>1 \u00b5L split (split ratio 20:1)<\/td><\/tr><tr><th class=\"sub conditions_header\" scope=\"row\">Liner:<\/th><td>Topaz 4.0 mm ID single taper inlet liner with wool (<a target=\"_blank\" href=\"https:\/\/www.restek.com\/p\/23303?utm_source=chromatograms&amp;utm_medium=link&amp;utm_campaign=GC_EV1606\" rel=\"noopener\">cat.# 23303<\/a>)<\/td><\/tr><tr><th class=\"sub conditions_header\" scope=\"row\">Inj. Temp.:<\/th><td>250 \u00b0C<\/td><\/tr><tr><th class=\"sub conditions_header\" scope=\"row\">Split Vent Flow Rate:<\/th><td>24 mL\/min<\/td><\/tr><tr class=\"cgram_header_row\"><th class=\"conditions_header\" scope=\"row\" colspan=\"2\">Oven<\/td><\/tr><tr><th class=\"sub conditions_header\" scope=\"row\">Oven Temp.:<\/th><td>40 &#176;C (hold 0.5 min) to 280 &#176;C at 20 &#176;C\/min to 330 &#176;C at 6 &#176;C\/min (hold 4 min)<\/td><\/tr><tr class=\"cgram_header_row\"><th class=\"conditions_header\" scope=\"row\">Carrier Gas<\/th><td>He, constant flow<\/td><\/tr><tr><th class=\"sub conditions_header\" scope=\"row\">Flow Rate:<\/th><td>1.2 mL\/min<\/td><\/tr><\/table><table class=\"conditions col-lg-6 col-12\"><tr><th class=\"conditions_header\" scope=\"row\">Detector<\/th><td>MS<\/td><\/tr><tr><th class=\"sub conditions_header\" scope=\"row\">Mode:<\/th><td>SIM<\/td><\/tr><tr><th class=\"sub conditions_header\" scope=\"row\">SIM Program:<\/th><td><\/td><\/tr><tr><td style=\"text-align:left\" colspan=\"2\"><table class=\"conditions_sim\"><thead><tr><th style=\"padding: 0 5px\">Group<\/th><th style=\"padding: 0 5px\">Start Time<br \/>(min)<\/th><th style=\"padding: 0 5px\">Ion(s) (m\/z)<\/th><th style=\"padding: 0 5px\">Dwell (ms)<\/th><\/tr><\/thead><tbody><tr><td style=\"vertical-align:top\">1<\/td><td style=\"vertical-align:top\">5.00<\/td><td>127.05, 128.05, 129.00 <\/td><td>10<\/td><\/tr><tr><td style=\"vertical-align:top\">2<\/td><td style=\"vertical-align:top\">6.75<\/td><td>115.10, 139.00, 141.00, 142.05 <\/td><td>10<\/td><\/tr><tr><td style=\"vertical-align:top\">3<\/td><td style=\"vertical-align:top\">7.47<\/td><td>141.00, 152.00, 153.05, 154.05, 155.05, 156.10, 162.10, 164.10 <\/td><td>10<\/td><\/tr><tr><td style=\"vertical-align:top\">4<\/td><td style=\"vertical-align:top\">8.03<\/td><td>150.00, 151.05, 152.05, 153.05, 154.10, 162.10, 164.10 <\/td><td>10<\/td><\/tr><tr><td style=\"vertical-align:top\">5<\/td><td style=\"vertical-align:top\">8.66<\/td><td>153.05, 155.10, 163.05, 164.10, 165.05, 166.05, 169.10, 170.10 <\/td><td>10<\/td><\/tr><tr><td style=\"vertical-align:top\">6<\/td><td style=\"vertical-align:top\">9.62<\/td><td>139.00, 151.95, 176.10, 177.10, 178.10, 179.10, 183.95, 185.00, 188.10, 189.10 <\/td><td>10<\/td><\/tr><tr><td style=\"vertical-align:top\">7<\/td><td style=\"vertical-align:top\">10.71<\/td><td>189.05, 190.05, 191.10, 192.10 <\/td><td>10<\/td><\/tr><tr><td style=\"vertical-align:top\">8<\/td><td style=\"vertical-align:top\">11.37<\/td><td>200.10, 201.10, 202.10, 203.05 <\/td><td>10<\/td><\/tr><tr><td style=\"vertical-align:top\">9<\/td><td style=\"vertical-align:top\">11.81<\/td><td>200.10, 201.05, 202.05, 203.05 <\/td><td>10<\/td><\/tr><tr><td style=\"vertical-align:top\">10<\/td><td style=\"vertical-align:top\">12.84<\/td><td>114.00, 120.00, 226.10, 227.10, 228.10, 229.10, 240.10 <\/td><td>10<\/td><\/tr><tr><td style=\"vertical-align:top\">11<\/td><td style=\"vertical-align:top\">14.44<\/td><td>126.00, 132.00, 250.10, 252.10, 253.10, 264.00 <\/td><td>10<\/td><\/tr><tr><td style=\"vertical-align:top\">12<\/td><td style=\"vertical-align:top\">15.51<\/td><td>126.00, 132.00, 250.05, 252.05, 253.05, 264.00 <\/td><td>10<\/td><\/tr><tr><td style=\"vertical-align:top\">13<\/td><td style=\"vertical-align:top\">16.95<\/td><td>137.95, 139.00, 274.05, 276.10, 277.10, 278.10, 279.10 <\/td><td>10<\/td><\/tr><tr><td style=\"vertical-align:top\">14<\/td><td style=\"vertical-align:top\">18.10<\/td><td>138.00, 274.05, 276.10, 277.10 <\/td><td>10<\/td><\/tr><\/tbody><\/table><\/td><\/tr><tr><th class=\"sub conditions_header\" scope=\"row\">Transfer Line Temp.:<\/th><td>280 \u00b0C<\/td><\/tr><tr><th class=\"sub conditions_header\" scope=\"row\">Analyzer Type:<\/th><td>Quadrupole <\/td><\/tr><tr><th class=\"sub conditions_header\" scope=\"row\">Source Type:<\/th><td>Extractor <\/td><\/tr><tr><th class=\"sub conditions_header\" scope=\"row\">Extractor Lens:<\/th><td>6 mm ID<\/td><\/tr><tr><th class=\"sub conditions_header\" scope=\"row\">Source Temp.:<\/th><td>330 \u00b0C<\/td><\/tr><tr><th class=\"sub conditions_header\" scope=\"row\">Quad Temp.:<\/th><td>150 \u00b0C<\/td><\/tr><tr><th class=\"sub conditions_header\" scope=\"row\">Tune Type:<\/th><td>DFTPP <\/td><\/tr><tr><th class=\"sub conditions_header\" scope=\"row\">Ionization Mode:<\/th><td>EI <\/td><\/tr><tr class=\"cgram_header_row\"><th class=\"conditions_header\" scope=\"row\">Instrument<\/th><td>Agilent 7890B GC &amp; 5977A MSD<\/td><\/tr><tr class=\"cgram_header_row\"><th class=\"conditions_header\" scope=\"row\">Sample Preparation<\/th><td>NIST SRM 1597a was diluted 5x in dichloromethane. Isotope-labeled IS\/SS are 20 pg on-column. Samples were aliquoted into amber 2 mL, 9 mm short-cap, screw-thread vials (<a target=\"_blank\" href=\"https:\/\/www.restek.com\/p\/21143?utm_source=chromatograms&amp;utm_medium=link&amp;utm_campaign=GC_EV1606\" rel=\"noopener\">cat.# 21143<\/a>) containing glass Big Mouth inserts (<a target=\"_blank\" href=\"https:\/\/www.restek.com\/p\/21782?utm_source=chromatograms&amp;utm_medium=link&amp;utm_campaign=GC_EV1606\" rel=\"noopener\">cat.# 21782<\/a>) and sealed with 2.0 mL, 9 mm short-cap, screw-vial closures (<a target=\"_blank\" href=\"https:\/\/www.restek.com\/p\/23842?utm_source=chromatograms&amp;utm_medium=link&amp;utm_campaign=GC_EV1606\" rel=\"noopener\">cat.# 23842<\/a>).<\/td><\/tr><tr class=\"cgram_header_row\"><th class=\"conditions_header\" scope=\"row\">Notes<\/th><td>The internal standard and surrogate standard mass on column is 20 pg.<\/td><\/tr><\/table><\/div><\/div><\/div><div class=\"chromatogram-pdf-link\"><a href=\"https:\/\/ez.restek.com\/images\/cgram\/gc_ev1606.pdf\" target=\"_blank\" rel=\"noopener noreferrer\"><svg xmlns=\"http:\/\/www.w3.org\/2000\/svg\" width=\"18\" height=\"18\" viewBox=\"0 0 18 18\"><g data-name=\"Group 2996\"><path data-name=\"Rectangle 1246\" d=\"M0 0h18v18H0z\" style=\"fill: none;\"><\/path><\/g><g data-name=\"Group 2997\"><path data-name=\"Path 729\" d=\"M13.412 11.4v2.017H5.345V11.4H4v2.017a1.349 1.349 0 0 0 1.345 1.345h8.068a1.349 1.349 0 0 0 1.345-1.345V11.4zm-.672-2.694-.948-.948-1.741 1.735V4H8.706v5.493L6.965 7.758l-.948.948 3.361 3.361z\" transform=\"translate(-.437 -.414)\" style=\"fill: rgb(13, 123, 196);\"><\/path><\/g><\/svg>Download PDF<\/a><\/div><\/div><\/div>\n<\/div><\/div><\/div>\n\n\n<div style=\"height:100px\" aria-hidden=\"true\" class=\"wp-block-spacer\"><\/div>\n\n\n        <div class=\"cpb\">\n            <h3 class=\"cpb-heading\">Products Mentioned<\/h3>\n            <hr class=\"cpb-heading-underline\" \/>\n            <div class=\"cpb-list\">\n                                    <div class=\"cpb-item\">\n                        <div class=\"cpb-col cpb-col--left\">\n                            <a class=\"cpb-catalog\" target=\"_blank\" rel=\"noopener noreferrer\" href=\"https:\/\/www.restek.com\/p\/16623\">                                Catalog No. 16623                            <\/a>                        <\/div>\n                        <div class=\"cpb-col cpb-col--middle\">\n                            <div class=\"cpb-title\">Rxi-SVOCms GC Capillary Column, 30 m, 0.25 mm ID, 0.25 \u00b5m<\/div>\n                        <\/div>\n                        <div class=\"cpb-col cpb-col--right\">\n                                                            <a class=\"cpb-view-btn\" target=\"_blank\" rel=\"noopener noreferrer\" href=\"https:\/\/www.restek.com\/p\/16623\">\u88fd\u54c1\u60c5\u5831\u3092\u898b\u308b<\/a>\n                                                    <\/div>\n                    <\/div>\n                                    <div class=\"cpb-item\">\n                        <div class=\"cpb-col cpb-col--left\">\n                            <a class=\"cpb-catalog\" target=\"_blank\" rel=\"noopener noreferrer\" href=\"https:\/\/www.restek.com\/p\/23303\">                                Catalog No. 23303                            <\/a>                        <\/div>\n                        <div class=\"cpb-col cpb-col--middle\">\n                            <div class=\"cpb-title\">Topaz, Single Taper Inlet Liner, 4.0 mm x 6.5 x 78.5, for Agilent GCs, w\/Quartz Wool, Premium Deactivation, 5-pk.<\/div>\n                        <\/div>\n                        <div class=\"cpb-col cpb-col--right\">\n                                                            <a class=\"cpb-view-btn\" target=\"_blank\" rel=\"noopener noreferrer\" href=\"https:\/\/www.restek.com\/p\/23303\">\u88fd\u54c1\u60c5\u5831\u3092\u898b\u308b<\/a>\n                                                    <\/div>\n                    <\/div>\n                                    <div class=\"cpb-item\">\n                        <div class=\"cpb-col cpb-col--left\">\n                            <a class=\"cpb-catalog\" target=\"_blank\" rel=\"noopener noreferrer\" href=\"https:\/\/www.restek.com\/p\/21143\">                                Catalog No. 21143                            <\/a>                        <\/div>\n                        <div class=\"cpb-col cpb-col--middle\">\n                            <div class=\"cpb-title\">Short-Cap Vial with Grad Marking Spot, 9-425 Screw-Thread, 2.0 mL, 9 mm, 12 x 32 (vial only), Amber, 1000-pk.<\/div>\n                        <\/div>\n                        <div class=\"cpb-col cpb-col--right\">\n                                                            <a class=\"cpb-view-btn\" target=\"_blank\" rel=\"noopener noreferrer\" href=\"https:\/\/www.restek.com\/p\/21143\">\u88fd\u54c1\u60c5\u5831\u3092\u898b\u308b<\/a>\n                                                    <\/div>\n                    <\/div>\n                                    <div class=\"cpb-item\">\n                        <div class=\"cpb-col cpb-col--left\">\n                            <a class=\"cpb-catalog\" target=\"_blank\" rel=\"noopener noreferrer\" href=\"https:\/\/www.restek.com\/p\/21782\">                                Catalog No. 21782                            <\/a>                        <\/div>\n                        <div class=\"cpb-col cpb-col--middle\">\n                            <div class=\"cpb-title\">Vial Inserts, Glass, Big Mouth w\/ Bottom Spring, 50 \u00b5L, 1000-pk.<\/div>\n                        <\/div>\n                        <div class=\"cpb-col cpb-col--right\">\n                                                            <a class=\"cpb-view-btn\" target=\"_blank\" rel=\"noopener noreferrer\" href=\"https:\/\/www.restek.com\/p\/21782\">\u88fd\u54c1\u60c5\u5831\u3092\u898b\u308b<\/a>\n                                                    <\/div>\n                    <\/div>\n                                    <div class=\"cpb-item\">\n                        <div class=\"cpb-col cpb-col--left\">\n                            <a class=\"cpb-catalog\" target=\"_blank\" rel=\"noopener noreferrer\" href=\"https:\/\/www.restek.com\/p\/23842\">                                Catalog No. 23842                            <\/a>                        <\/div>\n                        <div class=\"cpb-col cpb-col--middle\">\n                            <div class=\"cpb-title\">Short Screw Caps, Polypropylene, Ribbed, Screw-Thread, PTFE\/Silicone Lined, for Agilent 7693A, Blue, Preassembled, 2.0 mL, 9 mm, 1000-pk.<\/div>\n                        <\/div>\n                        <div class=\"cpb-col cpb-col--right\">\n                                                            <a class=\"cpb-view-btn\" target=\"_blank\" rel=\"noopener noreferrer\" href=\"https:\/\/www.restek.com\/p\/23842\">\u88fd\u54c1\u60c5\u5831\u3092\u898b\u308b<\/a>\n                                                    <\/div>\n                    <\/div>\n                            <\/div>\n        <\/div>\n        \n\n\n<div style=\"height:100px\" aria-hidden=\"true\" class=\"wp-block-spacer\"><\/div>\n","protected":false},"excerpt":{"rendered":"<p>\u591a\u74b0\u82b3\u9999\u65cf\u70ad\u5316\u6c34\u7d20 (PAH) \u306f\u3001\u534a\u63ee\u767a\u6027\u5316\u5408\u7269\u5206\u6790\u306b\u304a\u3044\u3066\u6700\u3082\u5206\u96e2\u304c\u96e3\u3057\u3044\u5316\u5408\u7269\u306e\u3072\u3068\u3064\u3067\u3059\u3002Rxi-SVOCms\u306f\u3001\u3053\u3053\u3067\u78ba\u7acb\u3057\u305f\u6761\u4ef6\u4e0b\u306723\u306e\u7279\u5b9a\u6c5a\u67d3\u7269\u8cea\u306e\u6700\u9069\u306a\u5206\u96e2\u3092\u5b9f\u73fe\u3057\u307e\u3059\u3002<\/p>\n","protected":false},"author":11,"featured_media":6732,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"_kad_blocks_custom_css":"","_kad_blocks_head_custom_js":"","_kad_blocks_body_custom_js":"","_kad_blocks_footer_custom_js":"","_kadence_starter_templates_imported_post":false,"_kad_post_transparent":"","_kad_post_title":"","_kad_post_layout":"","_kad_post_sidebar_id":"","_kad_post_content_style":"","_kad_post_vertical_padding":"","_kad_post_feature":"","_kad_post_feature_position":"","_kad_post_header":false,"_kad_post_footer":false,"footnotes":""},"categories":[789],"tags":[],"industries-application":[2271],"post-badge":[],"resource-type":[],"product-library":[2564,2566,2552],"resource-technique":[2340,2345],"ppma_author":[414],"class_list":["post-43499","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-articles-ja","industries-application-environmental-ja","product-library-gc-columns-ja","product-library-inlet-supplies-ja","product-library-gas-chromatography-products-ja","resource-technique-gas-chromatography-gc-ja","resource-technique-mass-spectrometry-ms-ja"],"acf":[],"taxonomy_info":{"category":[{"value":789,"label":"\u6280\u8853\u8cc7\u6599"}],"industries-application":[{"value":2271,"label":"\u74b0\u5883 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