{"id":48537,"date":"2012-02-29T13:30:00","date_gmt":"2012-02-29T13:30:00","guid":{"rendered":"https:\/\/discover.restek.com\/uncategorized\/japanese-can-i-analyze-no-n2o-and-no2-via-gc\/"},"modified":"2025-11-25T17:29:57","modified_gmt":"2025-11-25T17:29:57","slug":"japanese-can-i-analyze-no-n2o-and-no2-via-gc","status":"publish","type":"post","link":"https:\/\/discover.restek.com\/ja\/blogs-ja\/gnbl4595-ja\/japanese-can-i-analyze-no-n2o-and-no2-via-gc","title":{"rendered":"GC\u3067NO\u3001N2O \u3001NO2 \u306f\u5206\u6790\u3067\u304d\u307e\u3059\u304b?"},"content":{"rendered":"\n<figure class=\"wp-block-image\"><img decoding=\"async\" src=\"https:\/\/discover.restek.com\/wp-content\/uploads\/blog-can-i-analyze-no-n2o-and-no2-via-gc-01.jpg\" alt=\"2011-jaap-pasfoto4\" title=\"-\"><\/figure>\n\n\n\n<p>\u3053\u306e\u8cea\u554f\u306f\u6bce\u5e74\u4f55\u56de\u3082\u805e\u304b\u308c\u307e\u3059\u3002\u6614Chrompack\u793e\u3067\u4e00\u7dd2\u306b\u50cd\u3044\u3066\u3044\u305f Dick Zwiep \u306f\u3053\u306e\u8cea\u554f\u306b\u3001&nbsp;<em><strong>No \u3001 No-two!<\/strong><\/em>\u3068\u5197\u8ac7\u307e\u3058\u308a\u306b\u7b54\u3048\u3066\u3044\u307e\u3057\u305f\u3002<\/p>\n\n\n\n<p>\u554f\u984c\u306fN2O\u3067\u306f\u306a\u304f\u3001NO \u3068 NO2\u3067\u3059\u3002NO \u3068 NO2 \u306f\u53cd\u5fdc\u3057\u3084\u3059\u304b\u3063\u305f\u308a\u5e73\u8861\u72b6\u614b\u306b\u3042\u308b\u305f\u3081\u3001\u5b9a\u91cf\u306f\u56f0\u96e3\u3067\u3059\u3002<em><strong><\/strong><\/em><\/p>\n\n\n\n<p><strong>N2O(\u4e9c\u9178\u5316\u7a92\u7d20)<\/strong>\u306f\u201d\u7b11\u6c17\u30ac\u30b9\u201d\u3068\u3082\u547c\u3070\u308c\u3001GC\u3067\u5206\u6790\u3059\u308b\u306e\u306f\u3068\u3066\u3082\u7c21\u5358\u3067\u3059\u3002 Rt Q-BOND\u306e\u3088\u3046\u306a\u591a\u5b54\u6027\u30dd\u30ea\u30de\u30fc\u30bf\u30a4\u30d7\u306e\u56fa\u5b9a\u76f8\u3092\u7528\u3044\u3066\u5206\u6790\u3067\u304d\u307e\u3059(\u56f31. \u53c2\u7167)\u3002 N2O\u306e\u6eb6\u51fa\u306f\u304b\u306a\u308a\u65e9\u3044\u306e\u3067\u3001\u30b9\u30d7\u30ea\u30c3\u30c8\u6ce8\u5165\u304c\u9069\u3057\u3066\u3044\u307e\u3059\u3002\u3053\u306e\u30a2\u30d7\u30ea\u30b1\u30fc\u30b7\u30e7\u30f3\u3067\u306f\u691c\u51fa\u5668\u306bMS\u3092\u4f7f\u7528\u3057\u3066\u3044\u308b\u305f\u3081\u3001\u5185\u5f84 0.25mm\u306e PLOT \u30ab\u30e9\u30e0\u3092\u4f7f\u7528\u3057\u3066\u3044\u307e\u3059\u3002 N2O \u306e\u691c\u51fa\u306b\u306fECD\u3082\u3088\u304f\u4f7f\u7528\u3055\u308c\u307e\u3059\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image\"><img decoding=\"async\" src=\"https:\/\/discover.restek.com\/wp-content\/uploads\/blog-can-i-analyze-no-n2o-and-no2-via-gc-02.gif\" alt=\"decorative\" class=\"wp-image-4584\" title=\"-\"><\/figure>\n\n\n\n<p>\u56f31. \u4e9c\u9178\u5316\u7a92\u7d20\u306e\u30d4\u30fc\u30af\u306f Rt-Q-BOND\u306e\u591a\u5b54\u6027\u30dd\u30ea\u30de\u30fc\u304b\u3089\u5bfe\u79f0\u306a\u30d4\u30fc\u30af\u3068\u3057\u3066\u6eb6\u51fa\u3057\u3066\u304d\u307e\u3059\u3002<\/p>\n\n\n\n<p><strong>NO(\u4e00\u9178\u5316\u7a92\u7d20)<\/strong>\u306e\u6e2c\u5b9a\u306f\u304b\u306a\u308a\u56f0\u96e3\u3067\u3059\u3002\u9178\u7d20\u306b\u89e6\u308c\u308b\u3068\u3001&nbsp;NO\u306f\u8d64\u8910\u8272\u306eNO2 (\u4e8c\u9178\u5316\u7a92\u7d20)\u306b\u306a\u308a\u307e\u3059\u3002<\/p>\n\n\n\n<p>2 NO + O<sub>2<\/sub>&nbsp;\u2192 2 NO<sub>2<\/sub><\/p>\n\n\n\n<p>\u3053\u308c\u304c\u3053\u306e\u6e2c\u5b9a\u306e\u8ab2\u984c\u306e\u4e00\u3064\u3067\u3059\u3002NO\u306fO2\u3068\u76f4\u3061\u306b\u53cd\u5fdc\u3057\u307e\u3059\u3002 O2\u304c\u5b58\u5728\u3057\u306a\u3044\u5834\u5408\u306f\u3001NO\u306f\u307b\u3068\u3093\u3069\u306e\u30ab\u30e9\u30e0\u304b\u3089\u6eb6\u51fa\u3057\u3066\u304d\u307e\u3059\u304c\u3001\u4fdd\u6301\u306f\u6975\u3081\u3066\u5f31\u3044\u3082\u306e\u3067\u3059\u3002\u591a\u5b54\u6027\u30dd\u30ea\u30de\u30fc\u30bf\u30a4\u30d7\u306e\u56fa\u5b9a\u76f8\u3067\u3055\u3048\u3001\u6c38\u4e45\u30ac\u30b9\u3068\u5171\u6eb6\u51fa\u3057\u307e\u3059\u3002<\/p>\n\n\n\n<p>NO\u306f\u30e2\u30ec\u30ad\u30e5\u30e9\u30fc\u30b7\u30fc\u30d6\u30bf\u30a4\u30d7\u306e\u5438\u7740\u5264\u306b\u4fdd\u6301\u3055\u308c\u3001\u6e2c\u5b9a\u3059\u308b\u3053\u3068\u304c\u3067\u304d\u307e\u3059\u304c\u3001\u30d4\u30fc\u30af\u5f62\u72b6\u306f\u901a\u5e38\u5bfe\u79f0\u3067\u306f\u306a\u304f\u3001\u4f4e\u6fc3\u5ea6\u306e\u6e2c\u5b9a\u306f\u56f0\u96e3\u3067\u3059\u3002<\/p>\n\n\n\n<p>NO\/NO2 \u306e\u53cd\u5fdc\u901f\u5ea6\u8ad6\u306e\u30e2\u30c7\u30eb\u306b\u3064\u3044\u3066\u306f\u3001\u4e0b\u8a18\u3092\u3054\u53c2\u7167\u304f\u3060\u3055\u3044\uff1a<a href=\"http:\/\/www.chem.tamu.edu\/rgroup\/hughbanks\/courses\/102H\/lecturenotes\/class12-1.pdf\" target=\"_blank\" rel=\"noreferrer noopener\">http:\/\/www.chem.tamu.edu\/rgroup\/hughbanks\/courses\/102H\/lecturenotes\/class12-1.pdf<\/a><\/p>\n\n\n\n<p><strong>NO2 (\u4e8c\u9178\u5316\u7a92\u7d20)<\/strong>&nbsp;\u306fGC\u3067\u5206\u6790\u3059\u308b\u306e\u304c\u6700\u3082\u56f0\u96e3\u3067\u3059\u3002 NO<sub>2<\/sub>&nbsp;\u306fN<sub>2<\/sub>O<sub>4<\/sub>(\u56db\u9178\u5316\u4e8c\u7a92\u7d20)\u3068\u5e73\u8861\u72b6\u614b\u3067\u5b58\u5728\u3057\u307e\u3059:<\/p>\n\n\n\n<p>2 NO<sub>2<\/sub>&nbsp;&lt;=&gt;&nbsp;&nbsp;&nbsp;&nbsp; N<sub>2<\/sub>O<sub>4<\/sub><\/p>\n\n\n\n<figure class=\"wp-block-image\"><img decoding=\"async\" src=\"https:\/\/discover.restek.com\/wp-content\/uploads\/blog-can-i-analyze-no-n2o-and-no2-via-gc-03.gif\" alt=\"decorative\" class=\"wp-image-4585\" title=\"-\"><\/figure>\n\n\n\n<p><sub>\u56f32. \u30d3\u30cb\u30eb\u30d9\u30f3\u30bc\u30f3\u30d9\u30fc\u30b9\u306e\u591a\u5b54\u8cea\u30dd\u30ea\u30de\u30fc\u306eNO2\u3068\u306e\u53cd\u5fdc\u306b\u3088\u308a\u5b9a\u91cf\u306f\u56f0\u96e3\u306b\u306a\u308a\u307e\u3059\u3002<\/sub><\/p>\n\n\n\n<p>\u3053\u306e\u5206\u6790\u306b\u306f\u3044\u304f\u3064\u304b\u306e\u30a2\u30d7\u30ea\u30b1\u30fc\u30b7\u30e7\u30f3\u304c\u3042\u308a\u307e\u3059\u3002\u6700\u3082\u308f\u304b\u308a\u3084\u3059\u3044\u3082\u306e\u306f\u591a\u5b54\u8cea\u30dd\u30ea\u30de\u30fc\u3092\u4f7f\u7528\u3057\u305f\u3082\u306e\u3067\u3059\u304c\u3001\u4e8c\u9178\u5316\u7a92\u7d20\u306f\u591a\u5b54\u6027\u30dd\u30ea\u30de\u30fc\u3068\u53cd\u5fdc\u3057\u3066\u30a8\u30c1\u30ec\u30f3\u30d4\u30fc\u30af\u3092\u5f62\u6210\u3057\u307e\u3059(\u56f32.) \u3002\u3053\u308c\u306f\u5165\u308a\u53e3\u90e8\u5206\u306e\u71b1\u3067 NO2\u3092\u30a8\u30c1\u30ec\u30f3\u306b\u5909\u63db\u3059\u308b\u3053\u3068\u306b\u3088\u308a\u3001\u9593\u63a5\u7684\u306b NO2 \u3092\u6e2c\u5b9a\u3059\u308b\u65b9\u6cd5\u304b\u3082\u3057\u308c\u307e\u305b\u3093\u304c\u3001\u5909\u63db\u306f\u5b9a\u91cf\u7684\u3067\u306f\u306a\u3044\u3068\u8003\u3048\u3089\u308c\u307e\u3059\u3002<\/p>\n\n\n\n<p>NO2 \u5206\u6790\u306b\u6700\u9069\u306a\u30ab\u30e9\u30e0\u306f\u30b7\u30ea\u30ab\u30b2\u30eb\u306b\u306a\u308b\u3068\u63a8\u6e2c\u3067\u304d\u307e\u3059\u304c\u3001\u30c7\u30fc\u30bf\u306f\u9650\u3089\u308c\u3066\u3044\u307e\u3059\u3002<\/p>\n\n\n\n<p>\u4f4e\u6fc3\u5ea6\u306e\u691c\u51fa\u306b\u306fMS\u3001ECD\u304a\u3088\u3073PDD\u3092\u4f7f\u7528\u3067\u304d\u307e\u3059\u3002TCD\u3067\u3082\u691c\u51fa\u306f\u53ef\u80fd\u3067\u3059\u304c\u3001ppm\u30ec\u30d9\u30eb\u306e\u6e2c\u5b9a\u306e\u307f\u306b\u306a\u308a\u307e\u3059\u3002<\/p>\n\n\n\n<p>The original entry of this blog was posted on Thursday, March 1st,2012 at 10:10 am and is filed under Optimizing Applications.<\/p>\n\n\n\n<div style=\"height:100px\" aria-hidden=\"true\" class=\"wp-block-spacer\"><\/div>\n","protected":false},"excerpt":{"rendered":"<p>This question pops up a number of times every year. The joking answer my former colleague Dick Zwiep (when we both worked at Chrompack time) used to make was: No and No-two! The challenge is not the N2O, but the&#8230;<\/p>\n","protected":false},"author":19,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"_kad_blocks_custom_css":"","_kad_blocks_head_custom_js":"","_kad_blocks_body_custom_js":"","_kad_blocks_footer_custom_js":"","_kadence_starter_templates_imported_post":false,"_kad_post_transparent":"","_kad_post_title":"","_kad_post_layout":"","_kad_post_sidebar_id":"","_kad_post_content_style":"","_kad_post_vertical_padding":"","_kad_post_feature":"","_kad_post_feature_position":"","_kad_post_header":false,"_kad_post_footer":false,"footnotes":""},"categories":[794],"tags":[],"industries-application":[],"post-badge":[],"resource-type":[],"product-library":[],"resource-technique":[2340],"hf_cat_post":[623],"ppma_author":[439],"class_list":["post-48537","post","type-post","status-publish","format-standard","hentry","category-blogs-ja","resource-technique-gas-chromatography-gc-ja"],"acf":[],"taxonomy_info":{"category":[{"value":794,"label":"Blogs"}],"resource-technique":[{"value":2340,"label":"\u30ac\u30b9\u30af\u30ed\u30de\u30c8\u30b0\u30e9\u30d5\u30a3\u30fc"}]},"featured_image_src_large":false,"author_info":{"display_name":"Jaap de Zeeuw","author_link":"https:\/\/discover.restek.com\/ja\/author\/jaap-de-zeeuw\/"},"comment_info":0,"category_info":[{"term_id":794,"name":"Blogs","slug":"blogs-ja","term_group":0,"term_taxonomy_id":794,"taxonomy":"category","description":"","parent":0,"count":442,"filter":"raw","cat_ID":794,"category_count":442,"category_description":"","cat_name":"Blogs","category_nicename":"blogs-ja","category_parent":0}],"tag_info":false,"authors":[{"term_id":439,"user_id":19,"is_guest":0,"slug":"jaap-de-zeeuw","display_name":"Jaap de Zeeuw","avatar_url":{"url":"https:\/\/discover.restek.com\/wp-content\/uploads\/people-de-zeeuw-jaap.jpg","url2x":"https:\/\/discover.restek.com\/wp-content\/uploads\/people-de-zeeuw-jaap.jpg"},"0":null,"1":"","2":"","3":"","4":"","5":"","6":"","7":"","8":""}],"_links":{"self":[{"href":"https:\/\/discover.restek.com\/ja\/wp-json\/wp\/v2\/posts\/48537","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/discover.restek.com\/ja\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/discover.restek.com\/ja\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/discover.restek.com\/ja\/wp-json\/wp\/v2\/users\/19"}],"replies":[{"embeddable":true,"href":"https:\/\/discover.restek.com\/ja\/wp-json\/wp\/v2\/comments?post=48537"}],"version-history":[{"count":3,"href":"https:\/\/discover.restek.com\/ja\/wp-json\/wp\/v2\/posts\/48537\/revisions"}],"predecessor-version":[{"id":68849,"href":"https:\/\/discover.restek.com\/ja\/wp-json\/wp\/v2\/posts\/48537\/revisions\/68849"}],"wp:attachment":[{"href":"https:\/\/discover.restek.com\/ja\/wp-json\/wp\/v2\/media?parent=48537"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/discover.restek.com\/ja\/wp-json\/wp\/v2\/categories?post=48537"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/discover.restek.com\/ja\/wp-json\/wp\/v2\/tags?post=48537"},{"taxonomy":"industries-application","embeddable":true,"href":"https:\/\/discover.restek.com\/ja\/wp-json\/wp\/v2\/industries-application?post=48537"},{"taxonomy":"post-badge","embeddable":true,"href":"https:\/\/discover.restek.com\/ja\/wp-json\/wp\/v2\/post-badge?post=48537"},{"taxonomy":"resource-type","embeddable":true,"href":"https:\/\/discover.restek.com\/ja\/wp-json\/wp\/v2\/resource-type?post=48537"},{"taxonomy":"product-library","embeddable":true,"href":"https:\/\/discover.restek.com\/ja\/wp-json\/wp\/v2\/product-library?post=48537"},{"taxonomy":"resource-technique","embeddable":true,"href":"https:\/\/discover.restek.com\/ja\/wp-json\/wp\/v2\/resource-technique?post=48537"},{"taxonomy":"hf_cat_post","embeddable":true,"href":"https:\/\/discover.restek.com\/ja\/wp-json\/wp\/v2\/hf_cat_post?post=48537"},{"taxonomy":"author","embeddable":true,"href":"https:\/\/discover.restek.com\/ja\/wp-json\/wp\/v2\/ppma_author?post=48537"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}