Figure Heading 1
GC_EV1604
Peaks
| Peaks | tR (min) | |
|---|---|---|
| 1. | (IS) 1,4-Dioxane-d8 | 1.87 |
| 2. | <a class="cmpd_link" title="View compound information for N-Nitrosodimethylamine” title=”View compound information for N-Nitrosodimethylamine” href=”https://ez.restek.com/compound/view/en/62-75-9/N-Nitrosodimethylamine”>N-Nitrosodimethylamine | 2.00 |
| 3. | Pyridine | 2.03 |
| 4. | (SS) 2-Fluorophenol | 2.67 |
| 5. | (SS) Phenol-d6 | 3.29 |
| 6. | Phenol | 3.30 |
| 7. | Aniline | 3.36 |
| 8. | Bis(2-chloroethyl) ether | 3.40 |
| 9. | 2-Chlorophenol | 3.46 |
| 10. | 1,3-Dichlorobenzene | 3.59 |
| 11. | (IS) 1,4-Dichlorobenzene-D4 | 3.63 |
| 12. | 1,4-Dichlorobenzene | 3.65 |
| 13. | Benzyl alcohol | 3.72 |
| 14. | 1,2-Dichlorobenzene | 3.78 |
| 15. | 2-Methylphenol | 3.80 |
| 16. | Bis(2-Chloroisopropyl)ether | 3.84 |
| 17. | 4-Methylphenol | 3.93 |
| 18. | 3-Methylphenol | 3.93 |
| 19. | <a class="cmpd_link" title="View compound information for N-Nitrosodi-N-propylamine” title=”View compound information for N-Nitrosodi-N-propylamine” href=”https://ez.restek.com/compound/view/en/621-64-7/N-Nitrosodi-N-propylamine”>N-Nitrosodi-N-propylamine | 3.95 |
| 20. | Hexachloroethane | 4.07 |
| 21. | (SS) Nitrobenzene-D5 | 4.10 |
| 22. | Nitrobenzene | 4.11 |
| 23. | Isophorone | 4.32 |
| 24. | 2-Nitrophenol | 4.40 |
| 25. | 2,4-Dimethylphenol | 4.42 |
| 26. | Benzoic acid | 4.46 |
| 27. | Bis(2-chloroethoxy)methane | 4.51 |
| 28. | 2,4-Dichlorophenol | 4.61 |
| 29. | 1,2,4-Trichlorobenzene | 4.70 |
| 30. | (IS) Naphthalene-D8 | 4.76 |
| 31. | Naphthalene | 4.78 |
| Peaks | tR (min) | |
|---|---|---|
| 32. | 4-Chloroaniline | 4.82 |
| 33. | Hexachlorobutadiene | 4.89 |
| 34. | 4-Chloro-3-methylphenol | 5.26 |
| 35. | 2-Methylnaphthalene | 5.43 |
| 36. | 1-Methylnaphthalene | 5.53 |
| 37. | Hexachlorocyclopentadiene | 5.59 |
| 38. | 2,4,6-Trichlorophenol | 5.70 |
| 39. | 2,4,5-Trichlorophenol | 5.73 |
| 40. | (SS) 2-Fluorobiphenyl | 5.79 |
| 41. | 2-Chloronaphthalene | 5.91 |
| 42. | 2-Nitroaniline | 6.00 |
| 43. | 1,4-Dinitrobenzene | 6.13 |
| 44. | Dimethyl phthalate | 6.18 |
| 45. | 1,3-Dinitrobenzene | 6.20 |
| 46. | 2,6-Dinitrotoluene | 6.24 |
| 47. | 1,2-Dinitrobenzene | 6.29 |
| 48. | Acenaphthylene | 6.31 |
| 49. | 3-Nitroaniline | 6.40 |
| 50. | (IS) Acenaphthene-D10 | 6.45 |
| 51. | Acenaphthene | 6.48 |
| 52. | 2,4-Dinitrophenol | 6.50 |
| 53. | 4-Nitrophenol | 6.55 |
| 54. | 2,4-Dinitrotoluene | 6.63 |
| 55. | Dibenzofuran | 6.65 |
| 56. | 2,3,5,6-Tetrachlorophenol | 6.73 |
| 57. | 2,3,4,6-Tetrachlorophenol | 6.77 |
| 58. | Diethyl phthalate | 6.88 |
| 59. | 4-Chlorophenyl phenyl ether | 6.99 |
| 60. | Fluorene | 6.99 |
| 61. | 4-Nitroaniline | 7.00 |
| 62. | 4,6-Dinitro-2-methylphenol | 7.03 |
| Peaks | tR (min) | |
|---|---|---|
| 63. | <a class="cmpd_link" title="View compound information for N-Nitrosodiphenylamine” title=”View compound information for N-Nitrosodiphenylamine” href=”https://ez.restek.com/compound/view/en/86-30-6/N-Nitrosodiphenylamine”>N-Nitrosodiphenylamine | 7.10 |
| 64. | <a class="cmpd_link" title="View compound information for N,N-Diphenylhydrazine” title=”View compound information for N,N-Diphenylhydrazine” href=”https://ez.restek.com/compound/view/en/530-50-7/N,N-Diphenylhydrazine”>N,N-Diphenylhydrazine | 7.15 |
| 65. | (SS) 2,4,6-Tribromophenol | 7.23 |
| 66. | 4-Bromophenyl phenyl ether | 7.47 |
| 67. | Hexachlorobenzene | 7.53 |
| 68. | Pentachlorophenol | 7.72 |
| 69. | (IS) Phenanthrene-D10 | 7.92 |
| 70. | Phenanthrene | 7.94 |
| 71. | Anthracene | 7.99 |
| 72. | Carbazole | 8.15 |
| 73. | di-n-Butyl phthalate | 8.49 |
| 74. | Fluoranthene | 9.12 |
| 75. | Benzidine | 9.24 |
| 76. | (SS) Pyrene-D10 | 9.32 |
| 77. | Pyrene | 9.34 |
| 78. | (SS) p-Terphenyl-d14 | 9.49 |
| 79. | 3,3′-Dimethylbenzidine | 9.98 |
| 80. | Butyl benzyl phthalate | 10.00 |
| 81. | Bis(2-ethylhexyl) adipate | 10.09 |
| 82. | 3,3′-Dichlorobenzidine | 10.62 |
| 83. | Benz[a]anthracene | 10.66 |
| 84. | (IS) Chrysene-D12 | 10.67 |
| 85. | Chrysene | 10.71 |
| 86. | Bis(2-ethylhexyl) phthalate | 10.71 |
| 87. | Di-n-octyl phthalate | 11.68 |
| 88. | Benzo[b]fluoranthene | 12.30 |
| 89. | Benzo[k]fluoranthene | 12.34 |
| 90. | Benzo[a]pyrene | 12.89 |
| 91. | (IS) Perylene-D12 | 13.00 |
| 92. | Indeno[1,2,3-cd]pyrene | 15.32 |
| 93. | Dibenz[a,h]anthracene | 15.40 |
| 94. | Benzo[ghi]perylene | 15.95 |
All compounds are 2 ng on column.
Conditions
| Column | Rxi-SVOCms, 30 m, 0.25 mm ID, 0.25 µm (cat.# 16623) |
|---|---|
| Standard/Sample | |
| 8270 MegaMix standard (cat.# 31850) | |
| 8270 Benzidines mix (cat.# 31852) | |
| Benzoic acid (cat.# 31879) | |
| Revised SV internal standard mix (cat.# 31886) | |
| Revised B/N surrogate mix (cat.# 31888) | |
| Acid surrogate mix (cat.# 31063) | |
| Diluent: | Dichloromethane |
| Conc.: | 20 µg/mL |
| Injection | |
| Inj. Vol.: | 1 µL split (split ratio 10:1) |
| Liner: | Topaz 4.0 mm ID single taper inlet liner with wool (cat.# 23303) |
| Inj. Temp.: | 250 °C |
| Split Vent Flow Rate: | 12 mL/min |
| Oven | |
| Oven Temp.: | 60 °C (hold 0.5 min) to 285 °C at 25 °C/min to 305 °C at 3 °C/min to 330 °C at 20 °C/min (hold 5 min) |
| Carrier Gas | He, constant flow |
| Flow Rate: | 1.2 mL/min |
| Detector | MS | ||||||||
|---|---|---|---|---|---|---|---|---|---|
| Mode: | Scan | ||||||||
| Scan Program: | |||||||||
| |||||||||
| Transfer Line Temp.: | 280 °C | ||||||||
| Analyzer Type: | Quadrupole | ||||||||
| Source Type: | Inert | ||||||||
| Drawout Plate: | 6 mm ID | ||||||||
| Source Temp.: | 330 °C | ||||||||
| Quad Temp.: | 180 °C | ||||||||
| Electron Energy: | 70 eV | ||||||||
| Tune Type: | DFTPP | ||||||||
| Ionization Mode: | EI | ||||||||
| Instrument | Agilent 7890A GC & 5975C MSD | ||||||||
| Sample Preparation | Samples were aliquoted into amber 2 mL, 9 mm short-cap, screw-thread vials (cat.# 21143) containing glass Big Mouth inserts (cat.# 21782) and sealed with 2.0 mL, 9 mm short-cap, screw-vial closures (cat.# 23842). | ||||||||
GC_FF1390
Peaks
| Peaks | tR (min) | |
|---|---|---|
| 1. | Acetaldehyde | 5.410 |
| 2. | Methanol | 5.634 |
| 3. | Ethanol | 7.026 |
| 4. | 1-Propanol | 9.492 |
| 5. | Ethyl acetate | 10.321 |
| 6. | Isobutanol | 11.387 |
| 7. | Acetal | 13.138 |
| 8. | 3-Methyl-1-butanol | 14.334 |
| 9. | 2-Methyl-1-butanol | 14.420 |
| 10. | Propylene glycol | 15.749 |
Conditions
| Column | Rtx-1301, 60 m, 0.25 mm ID, 1.0 µm (cat.# 16056) |
|---|---|
| Standard/Sample | Rum (neat) |
| Diluent: | n/a |
| Injection | |
| Inj. Vol.: | 1 µL split (split ratio 100:1) |
| Liner: | Topaz, precision inlet liner, 4.0 mm x 6.3 x 78.5, with wool (cat.# 23305) |
| Inj. Temp.: | 250 °C |
| Split Vent Flow Rate: | 144.4 mL/min |
| Oven | |
| Oven Temp.: | 35 °C (hold 3 min) to 220 °C at 8 °C/min (hold 5 min) |
| Carrier Gas | He, constant flow |
| Flow Rate: | 1.4 mL/min |
| Linear Velocity: | 25.457 cm/sec @ 35 °C |
| Detector | FID @ 250 °C |
|---|---|
| Make-up Gas Flow Rate: | 25 mL/min |
| Make-up Gas Type: | N2 |
| Hydrogen flow: | 35 mL/min |
| Air flow: | 400 mL/min |
| Data Rate: | 50 Hz |
| Instrument | Agilent 7890A GC |
