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Seven EPA Methods on One Column Pair Using a micro-ECD

Analyze Pesticides, PCBs, Herbicides and More on a Single Rtx-CLPesticides Column Set

01 Nov 2020

feature EVSS1013

Analyze Pesticides, PCBs, Herbicides and More on a Single Rtx-CLPesticides Column Set, Using a micro-ECD and Dual Column Analysis

Get fast separations without sacrificing resolution by using Restek’s proprietary Rtx-CLPesticides and Rtx-CLPesticides2 columns for multiple environmental methods. Instead of changing columns between GC-ECD methods, you can save time by analyzing chlorinated pesticides, PCBs, herbicides, and other halogenated compounds on a single column set using dual column analysis and an Agilent micro-ECD. As shown here, Rtx-CLPesticides and Rtx-CLPesticides2 columns have a unique selectivity and are ideal for multiple GC-ECD methods. Compare them to your current column set and you’ll see the Restek advantage!

Rtx-CLPesticides columns offer the best overall performance for organochlorine pesticides analysis, as well as many other dual column analysis GC-ECD methods (0.32 mm ID columns).

Method Compound ListColumn PairAnalysis Time (min)CoelutionsRestek Advantage
8081B
(Organochlorine pesticides analysis)
Rtx-CLPesticides /
Rtx-CLPesticides2
7 / 70 / 0Increase sample throughput with 7 min analyses and baseline resolution.
Competitor A
column 1 / column 2
7 / 80 / 1
Competitor B
column 1 / column 2
10 / 90 / 0
 
8081B (extended)(Organochlorine pesticides analysis)Rtx-CLPesticides /
Rtx-CLPesticides2
24 / 231 / 2Best balance of speed and selectivity.
All compounds are resolved on at least one column.
Competitor A
column 1 / column 2
27 / 290 / 3
Competitor B
column 1 / column 2
NDP / 16NDP / 3
 
8082A
(Polychlorinated biphenyls [PCBs], Aroclors analysis)
Rtx-CLPesticides /
Rtx-CLPesticides2
7 / 7n/aFast PCB analysis times.
Competitor A
column 1 / column 2
6 / 7n/a
Competitor B
column 1 / column 2
24 / 21n/a
 
8151A
(Chlorinated herbicides analysis)
Rtx-CLPesticides /
Rtx-CLPesticides2
13 / 131 / 0More elution order changes improve confidence in confirmational results.
Competitor A
column 1 / column 2
13 / 130 / 0
Competitor B
column 1 / column 2
16 / 151 / 1
 
504.1
(EDB, DBCP, TCP analysis)
Rtx-CLPesticides /
Rtx-CLPesticides2
6 / 60 / 0Reliably separate analytes from trihalomethane interferences.
Competitor A
column 1 / column 2
6 / 60 / 0
Competitor B
column 1 / column 2
NDPNDP
 
505
(Organohalide pesticides analysis)
Rtx-CLPesticides /
Rtx-CLPesticides2
18 / 18.51 / 1All compounds resolved on at least one column.
Competitor A
column 1 / column 2
14 / 140 / 1
Competitor B
column 1 / column 2
35 / 361 / 2
 
508.1
(Chlorinated pesticides, herbicides, organohalides analysis)


Competitor A
column 1 / column 2
21 / 230 / 3Good balance of speed and resolution.
Competitor A
column 1 / column 2
21 / 230 / 3
Competitor B
column 1 / column 2
18 / 172 / 4
 
552.2
(Haloacetic acids, dalapon analysis)


Rtx-CLPesticides /
Rtx-CLPesticides2
12 / 120 / 0No coelutions—get accurate results for compounds that coelute on other columns.
Competitor A
column 1 / column 2
8 / 91 / 1
Competitor B
column 1 / column 2
NDP / 10NDP / 1

Comparison based on published competitor data. All columns tested were 0.32 mm ID. NDP = no data published.

NOTE: Analyzing dirty or derivatized samples can contaminate your column. Restek does not recommend analyzing trace-level pesticide samples following derivatized samples (e.g., Methods 8151A and 552.2) without first performing inlet maintenance. Standard steps include trimming the guard column and changing the inlet liner, seal, O-ring, and septum.

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  • Restek Corporation

    Restek is a leading provider of chromatography columns, accessories, and certified reference materials. Trust Restek for reliable, high-quality analytical solutions.

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EVSS1013
Version: F